Definitions you need to know - Solubility -Entropy: how far?

Lattice Energy is the enthalpy change (energy released) when one mole of an ionic solid is formed from its constituent gaseous ions infinitely far apart.

Xa+ (g) +Yb- (g) → XbYa (s)   ΔH lattice



Enthalpy change of hydration is the enthalpy change (energy released) when one mole of gaseous ions dissolved in sufficient solvent to given infinity dilute solution.

Xa+ (g) + aq → Xa+ (aq)     ΔHhyd (Xa+)

Yb- (g) + aq→ Yb- (aq)      ΔHhyd (Yb-)



Enthalpy change of solution is the enthalpy change when one mole of a compound is dissolved in sufficient solvent to give an infinitely dilute solvent.

XbYa (s) + aq→ XbYa (aq)  

ΔH solution =  -ΔH lattice + ΔHhyd (Xa+) + ΔHhyd (Yb-)



An Infinitely dilute solvent is a solution in which further dilution does not cause a heat change.

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